Sleeveless transparent optical disc storage unit

ABSTRACT

Novel optical disc storage units comprising transparent polypropylene are provided. Such storage units exhibit sufficient impact resistance to protect the target disc and sufficient clarity that any informational literature may be placed entirely within the storage unit and easily viewed and read through the walls thereof without impediment. Furthermore, the target storage unit must also include a spine section of sufficient width to permit a section of the informational literature to be placed internally thereon and viewed and easily read (such as, for example, the title and accompanying language describing the target disc placed therein) substantially without impediment as well. Specific novel storage units, in addition to these necessarily transparent walls and spine portions, are also possible to maximize the benefits of the transparent properties thereof.

This is a Divisional Application of earlier co-pending application Ser.No. 10/215,724, filed on Aug. 10, 2002 the contents of which are herebyincorporated by reference in their entirety.

FIELD OF THE INVENTION

This invention relates to novel optical disc storage units comprisingtransparent polypropylene. Such storage units exhibit sufficient impactresistance to protect the target disc and sufficient clarity that anyinformational literature may be placed entirely within the storage unitand easily viewed and read through the walls thereof without impediment.Furthermore, the target storage unit must also include a spine sectionof sufficient width to permit a section of the informational literatureto be placed internally thereon and viewed and easily read (such as, forexample, the title and accompanying language describing the target discplaced therein) substantially without impediment as well. Specific novelstorage units, in addition to these necessarily transparent walls andspine portions, are also possible to maximize the benefits of thetransparent properties thereof.

DISCUSSION OF THE PRIOR ART

Optical data storage discs, such as compact discs (CDs), digital videodiscs (DVDs), and compact discs having read-only memory (CD-ROMs), havebeen utilized within the entertainment and computer field for a numberof years, with DVDs recently entering the market with much higheramounts of available encoded information for more impressive videoresults. Such discs generally comprise a layer of plastic material, onone side of which is formed a micro-relief pattern in the form ofindentations which comprise an encoded information signal. Thisinformation-containing side exhibiting such a micro-relief pattern isthen provided with a lacquer-protected metallized reflective layer topermit reading via a laser sensor. DVDs may contain more than one suchlayer of micro-relief patterns thus providing increased amount ofinformation. Such DVDs exhibit several formats but always comprise twosubstrates, each formed with at least one information layer, that aresecured to one another. Furthermore, the lacquered portion of the disc,generally being solely on one side, usually is provided with visibleprinted information for identification, informational, and/or aestheticpurposes to the user. Standard and particular production methods forsuch discs are disclosed within such documents as U.S. Pat. No.6,165,391 and European Patent EP 0608358B1 (including the production ofdiscs including holographic images embossed in the lacquer forming theprotective layer for the metallized surface in order for themicro-relief pattern to define such an holographic image).

Such optical discs are normally formed from polycarbonate material whichis injected into an injection molding machine in which a stamper ispresent, the stamper forming the pattern of indentations in thesubsequently formed disc to provide the encoded signal. Other techniquesutilize compression molding with a specific mold to provide the encodedsignals therein.

The discs may thus include certain holographic images on the surface aswell as different additives within the plastic layer, all notdetrimental to the operation of the target disc itself which can beutilized for anti-counterfeit purposes. However, such measures aregenerally available only upon removal from storage units (primarily forDVDs which are packaged mostly within opaque black storage units or, ifclear polypropylene is utilized, including informational literature onthe outside of the storage unit within clear sleeves, which in turnprevents viewing of the internal portion of the storage unit as well).There is thus a desire to provide such anti-counterfeit orauthentication benefits without the need to open a target unit.

Furthermore, storage units for such discs have predominately been eitherpolystyrene in nature (for CDs and CD-ROMs) or black (and thus opaque)polypropylene (for DVDs). Polystyrene is generally very clear and hasbecome commonplace in terms of CD and CD-ROM storage; however, suchmaterial has proven to be less than reliable in terms of long-termusage. Polystyrene is generally susceptible to breakage easily, requiresa two piece case to provide a hinge, and is more expensive thanpolyolefins. Opaque polypropylene prevents the ability to view theactual disc prior to opening of the unit itself. Polypropylenewithstands certain forces better than polystyrene (such as accidentaldrops, colliding with solid objects, etc.), and is cheaper than such anexpensive material. Furthermore, transparent polypropylene has beenutilized to a certain degree as well to reduce costs in other ways. Forexample, DVDs generally include an attached sleeve to the target storageunit of transparent thin film in order to place an identifyingpublication therein. Such a thin film sleeve increases costs to such adegree that certain storage unit producers have noted the ability toremove the need for such a costly thin film sleeve and move thepublished identification papers within the storage unit itself. Thus, ithas been determined that with sufficient transparency, the identifyingpublications can be viewed without opening the box itself. Furthermore,with regard to the anti-counterfeit measures (for example, holographspresent on the surface of a target disc), it has been determined thatremoval of sleeves (or jackets) and moving away from opaque, blackpolypropylene can accord the desired characteristics while not requiringfirst opening a target storage unit. However, it has also been foundthat this benefit is available only with a completely transparentstorage unit exhibiting sufficient clarity throughout that a sleeve (orjacket) for certain informational literature on the outside of the unitcan be avoided. This requirement has not been provided to date,particularly with a spine portion of a target storage unit that issufficiently transparent throughout to provide proper viewing andreading therethrough of the necessary informational literature forlibrary storage purposes.

Unfortunately, even with such previous developments in storage unitdesign and production as all-transparent boxes, there has been a lack ofmaximization of such a development, particularly in terms of reducingcosts associated with informational literature. In the past, booklets oflimited size have been produced for informational purposes for the user.Such booklets were placed within the storage unit but normally requiredremoval from the storage unit itself prior to reading. Such bookletsalso cost a great deal of money to produce and pack. There thus existsthe need to maximize the benefits of having the full publishedinformation documentation within the inside of the target disc storageunit. To date, for example, there still exists a standard configurationwherein the discs as stored remain within the storage unit and thus actas obstacles to reading the provided printed information literatureaccompanying the disc itself. To date, there has been no discussion orfair suggestion on how best to maximize such a limited design in orderto maximize the benefits of utilizing transparent polyolefin storageunit materials themselves. In particular, the ability to provide allpolypropylene storage units (and the accompanying benefits) haveheretofore gone unexplored. Thus, no mention of the ability to bring allinformational literature within such a storage unit has beenaccomplished, particularly where all of the transparent parts of thepolypropylene storage unit have been properly designed to permitcomplete, unimpeded viewing of the informational literature within theunit itself when in the closed position. Thus, such a completelytransparent polypropylene storage unit with all informational literatureplaced internally and easily readable while such a unit is closed hasnot been accorded these particular industries to date.

OBJECTS AND SUMMARY OF THE INVENTION

It is thus an object of this invention to provide a completelypolypropylene optical disc storage unit with all informationalliterature present within and easily viewed and readable while the unitis closed. Another object is to provide a living hinged storage unit(for simplified manufacturing) with a spine component of sufficientwidth to permit an area of informational literature for, as one example,a title for the particular disc itself, wherein the spine is essentiallyfree from any refractive impediments in the area in which the text ofthe informational literature is present. Yet another object of theinvention is to provide a simultaneous manner of efficient storage ofdiscs and improved access to provided informational literatureaccompanying such discs.

Accordingly, this invention encompasses a transparentpolypropylene-containing storage unit having a first side and a secondside separated by at least one living hinge and at least one spineportion, wherein said spine portion is substantially free from anyrefractive impediments (e.g., reinforcements and polymer injectionpoints), wherein when said storage unit is in its closed position andincluding informational literature therein, said informationalliterature can be viewed and read through the walls and spine of saidstorage unit. Also encompassed within this invention is a transparentpolypropylene-containing storage unit having a first side and a secondside separated by at least one living hinge and at least one spineportion having a top peripheral edge and a bottom peripheral edge,wherein said spine portion comprises a top end which extends from saidtop peripheral edge of said spine portion downward a distance equal toat most 5% of the height of the entire spine portion to either a definedor imaginary line parallel to said top peripheral edge, wherein saidspine portion comprises a bottom end which extends from the bottomperipheral edge of said spine portion upward a distance equal to at most5% of the height of the entire spine portion to either a defined orimaginary line parallel to said bottom peripheral edge, with theremainder of said spine portion constituting a middle area, wherein saidmiddle area is free from any refracting impediments, wherein when saidstorage unit is in its closed position and including informationalliterature therein, said informational literature can be viewed and readthrough the walls and said middle area of said spine of said storageunit. Further encompassed within this invention is either of the samestorage units defined above, which further includes at least oneperipheral edge, as noted above including at least one means for holdingsaid optical disc storage, said at least one disc holding means beingattached either permanently or temporarily to said at least oneperipheral edge via a hinge, wherein said optical disc may be maneuveredoutside of said storage unit while simultaneously being held within saiddiscs holding means which in turn remains attached to said at least oneperipheral edge of said storage unit.

DESCRIPTION OF THE INVENTION

Such a novel configuration as defined above solves a number of differentproblems, mostly associated with cost issues, to provide a relativelyinexpensive, yet effective storage unit for optical disc articles. Suchoptical disc articles are generally stored within thermoplasticcontainers that, in the past, have been, at least temporarily,aesthetically pleasing and protective. However, past compact disc (CD)storage units have utilized polystyrene which cannot be injected moldedinto living hinge arrangements, is highly susceptible to breakage fromtypical use situations, not to mention mere mishandling and/or dropping,and is relatively expensive both from a base polymer standpoint and alabor intensive perspective. More recent boxes for optical discs(including, without limitation, compact discs, CD-ROM, CD-R, DVD, andthe like articles) have been stored in a variety of thermoplasticcontainers, both when placed on a salesperson's shelf, as well as withina user's home or office. Some polypropylene, black (the majority of DVD)and clarified (much fewer DVDs and very few CD, CD-ROM, and CD-R) hasbeen utilized in certain situations, but none which include “book”containers that include unimpeded spine portions for viewing ofinformational material therethrough. In fact, transparent has proven, inthe past, to be less economically attractive than black polypropylenedue to the requirement that a clear jacket be utilized for both types ofcontainers for certain informational literature on the outside of thecontainer, but still integrally a part of the entire storage unit(primarily because clarity is not to a low enough level to permit fullviewing and reading of anything within the target storage unit. Hazinesscreates refraction problems such that definition in printed matterplaced inside such a unit is lacking from a reader's perspective to toogreat an extent for current use of all transparent PP storage units forsuch a purpose. Aesthetically, as well, such lack of sufficient claritycreates a storage unit that appears less than stellar, particularly whencoupled with optical discs that are generally high-end purchases andthus require aesthetics of the highest quality as well. Thus, theutilization of a clear sleeve or jacket is prevalent to provide suchaesthetically pleasing appearances to optical disc storage units, not tomention to facilitate locating and reading titles, and the like. Asnoted above, however, there is a distinct desire and/or need to avoidthe costs and labor required to omit the need for such a clear sleeve orjacket component. Furthermore, most informational literature is todayprinted in booklet form, folded, and placed within a securing system onthe internal portion of such a polypropylene-based storage unit. Thecosts involved with such a booklet is relatively high as well, not tomention the requirement that the user actually remove the informationalbooklet in order to read such material. The above defined novelconfiguration thus permits utilization of all transparent polypropylenefor placement of all informational material within the target storageunit with the ability to place greater amounts of information on suchmaterial available and directly viewable once the storage unit isopened.

Furthermore, heretofore unexplored within this industry is the need toprovide an unimpeded spine to facilitate viewing of any informationalliterature present within the storage unit within that area. As is wellknown, optical disc storage units typically include clear spines inorder to permit a title to be read while a plethora of such discs arekept in a library type formation. However, such clear spines have eitherbeen provided via the aforementioned easily breakable polystyrenecontainers (for CD and CD-ROM articles, for example) that further arenot able to include a living hinge. As well, standard black (opaque)polypropylene and, to a much lesser extent in number used today, clearpolypropylene, clear jackets are attached to the storage unit forinclusion of such informational material and thus to facilitate viewingof the title (and other desired information) on the spine for theaforementioned library configuration. Cost and complexity ofmanufacturing are both issues confronted with such jacket sleeves andtheir present necessity to provide the ultimate user (if not thesalesperson) a manner of storing and displaying his optical disc libraryin an arrangement that facilitates locating desired optical discsquickly and conveniently. Thus, the inventive optical disc storage unitsnoted above overcome these cost and manufacturing complexity problems aswell.

As used for this specific invention, the term “refractive impediments”is intended to encompass a range of possibilities. Initially, it isimportant to note that with any clear polymer, any modification at thesurface or within the polymer itself can create refraction differencesbetween the polymer and the modification site, thereby causingdistortions in appearance of any articles present on the other side ofthe clear polymer from the viewer. The general problem has thus beennoticed and avoided within the above-defined invention by removingrefractive impediments in the spine (the area used for quickidentification and location of target discs in a library set-up). Thus,the term “refractive impediments”, to one extreme, encompasses anyreinforcements (such as are typical within optical disc storage units toimpart improved flexural modulus and other strength characteristics tothe unit itself) or polypropylene injection points. Injection molding isthe typical method of producing polypropylene-containing articles ofthis type, e.g., boxes. As is generally and well known within thepolypropylene art, injection molding is the most convenient andcost-effective method of producing such articles. The molten polymer isinjected into a mold through a single point and the molten polymer thenflows across and/or within the mold evenly to form the desired shape,and ultimately, article, upon cooling within the mold itself. As mostoptical storage units made from polypropylene have been designedsymmetrically, the injection point or points are usually located in theexact center of the mold to provide the most even distribution ofpolymer. This is usually within the area that ultimately constitutes thespine portion of the target storage unit. Thus, to reiterate, at oneextreme of the range of possibilities encompassing the term “norefractive impediments”, no injection points or reinforcements will belocated within the spine portion of the target storage (eitherexternally or internally). To the other extreme, the term “refractiveimpediments” may include the presence of injection points, as well asreinforcements (again, either externally or internally), within thetarget area; however, in order to avoid the refraction problems, suchpoints or reinforcements can either be small enough not to impede theview of any informational literature pressed against the spine(internally within the storage unit), or clarified to such a degree thatthe refraction index of the polymer and such points or reinforcementsare essentially the same (thus no difference in appearance is noticedviewing any informational literature therethrough).

Furthermore, there can be, in one preferred embodiment, a top end of thespine portion and a bottom end of the spine portion, within which anynumber of reinforcement and/or injection points may be present. Suchends are generally within the areas so close to the top and bottom ofthe spine portion that the informational literature in such areas isgenerally not utilized to any necessary degree. Thus, there exists theability to leave a middle area between the top and bottom ends of thespine portion within which all of the desired informational material(title, description, etc.) may be placed without any impediment toviewing or reading. In such a situation, the user can, as above, stillutilize the target storage unit in a library configuration to facilitatequick location upon demand. The top end in such a scenario is thus anarea measured from the top peripheral edge of the spine portion downwardto a line parallel with said top peripheral edge. Such a line may beclearly demarcated or imaginary, depending on the molder's needs ordesires; however, at most such a line should be a distance equal to atmost 5% of the entire height of the spine portion itself. The bottom endis thus the same in structure and configuration, except that the lineand measurement is made from the bottom peripheral edge of the spineportion. Thus, the remaining middle area leaves sufficient room for anyinformational literature placed in contact with the internal spineportion (in relation to the storage unit) to provide the desiredmaterial for viewing and/or reading by the user. The distance of theline from either the top or bottom end that in turn defines the middlearea of the spine portion is preferably less than 5% of the height ofthe spine portion, and should be as low as possible. For a standardstorage unit, generally 7.5 inches in height, it is preferable that sucha distance be at most 0.375 inches, more preferably 0.25 inches, andmost preferably at most 0.15 inches. Again, this permits a clear,unimpeded view of any informational literature placed inside the storageunit and in contact with the internal spine portion which thus permitscomplete removal of any need to provide a clear jacket for such apurpose.

The utilization of a holding means (such as a rosette, a tray, or likecomponent) which is attached to the peripheral edge of the storage unit,preferably on either of the first or second sides thereof, is importantto permit the manufacturer and distributor to avoid the costs involvedwith providing informational literature in booklet form. Such aperipheral edge attachment permits moving of the holding means outsidethe storage unit when opened. Thus, a completely flat sheet containingall necessary information can be provided and placed within the targetstorage unit. Moving the holding means thus permits the user to view theentire contents of such a sheet without removing it itself from thestorage unit first. Generally, booklets of informational literature areheld in place by brackets; with such brackets the booklet is notdesigned to open unless removed therefrom. Furthermore, if any portionof such a booklet is present outside any such bracket, the targetstorage unit is generally difficult to close. In any event, the problemsassociated with such booklets, whether cost, convenience, storage unitclosure, etc., have dictated a desire to avoid such specificinformational literature configurations. The movable disc holding meansof this invention thus provides the basis for avoiding such noticeableproblems. Again, a full sheet, rather than a booklet, can be utilizedand the side of such a sheet placed against the internal portion of thestorage unit can be easily viewed and read when the unit is closed andthe remainder can be easily viewed and read when the unit opened and thedisc holding means is moved outside the unit as well.

Holographic images have been produced within the micro-relief pattern(s)of optical discs in the protective lacquer in order to provideauthentication or anti-counterfeiting techniques. In the past, however,such images required first removing the target disc from its storageunit prior to viewing such an anti-counterfeit marking device. Thus, theability to provide a simpler method of counterfeit detection viatransparent storage unit materials, and configuration of the particularstorage unit itself, has not been previously investigated. With such atransparent storage unit, the aforementioned benefits of moving theidentification literature within the case provides some difficulty indetermining proper views of the authenticity image (herein defined as aholographic image, a bar-code, or other like imaging effect thatindicates uniqueness of source). If the literature is too large in sizeand thus only permits viewing at the peripheral edges (as with the otherpreferred embodiment noted above), then either openings may be providedin the literature for proper viewing of the authenticity image atspecified areas of the target disc, or the authenticity image may alsobe placed on the peripheral edges for proper viewing and analysis by thetarget audience.

The transparency of the storage unit is of utmost importance forpermitting both readability of informational literature and, if desired,authenticity detection (such as, for example, through the presence ofholographs on the target disc). In such a manner, the ability to readinformational literature and to determine counterfeit discs while thestorage unit is either closed, sealed, or both, is not only facilitated,but also permitted. With promotional literature material utilized,either within a sleeve, or placed within the storage unit itself,generally such paper material is placed in such a way as to prevent easyview of the surface of the target disc. Thus, there is a need to eitherprovide a cut-out pattern within the promotional material or smallermaterial in general, to permit viewing of the surface of the target discif such anti-counterfeit (authenticity) measures are desired. Thetransparency of the storage unit material thus accords the ability toactually view the surface without removing the target disc from such acase.

For this purpose, polypropylene is most highly desired, in particularclarified polypropylene (cPP). Any standard clarifying agent may beutilized for this purpose, however, highly preferred are those of thesubstituted benzylidene sorbitol type, most highly preferred being3,4-dimethyldibenzylidene sorbitol (available from Milliken & Companyunder the tradename MILLAD® 3988 (MILLAD® 3940 may also be utilized;however, due to plate-out and organoleptic issues, such an additive isnot as highly desired for such a purpose). material in the reaction.Such an additive is indicated within U.S. Pat. No. 5,731,474 to Scrivenset al., for example, and is generally added to target polypropylene inan amount of from about 0.01 to about 2 percent by weight, preferablyabout 0.1 to about 1 percent by weight, based upon the total weight ofthe composition may be provided.

The cPP may be of any type that can be clarified to the levels neededfor ease in viewing and reading any informational literature within thestorage unit. The thickness of the walls and spine portion should befrom about 0.1 to about 100 mils, with a range of from 5 to about 50mils potentially preferred for both strength and transparency purposes.Such cPP thus may be PP homopolymer (HP), random copolymer PP(RCP)blended with other polyolefins or other types of comonomers as notedbelow (prereferably ethylenically unsaturated comonomers), as well assyndiotactic PP (although such a PP is more costly than the others).Generally, the comonomers, if present, constitute a minor amount, e.g.,about 10 percent or less or even about 5 percent or less, of the entirepolyolefin, based upon the total weight of the polyolefin. Suchcomonomers may serve to assist in clarity improvement of the polyolefin,or they may function to improve other properties of the polymer.Examples include acrylic acid and vinyl acetate, etc. Such PP can thusbe present alone or blended with various thermoplastics, such as,without limitation, aliphatic monoolefins or other monomers containing 2to about 6 carbon atoms which have an average molecular weight of fromabout 10,000 to about 2,000,000, preferably from about 30,000 to about300,000, such as polyethylene, linear low density polyethylene,crystalline ethylenepropylene copolymer, poly(1-butene), 1-hexene,1-octene, vinyl cyclohexane, and polymethylpentene, again, as long asthe clarity is low enough for the objects described and discussed above.

The preferred polypropylene composition can be obtained by adding aspecific amount of the substituted dibenzylidene sorbitol directly tothe polypropylene (or copolymer), and merely mixing them by an suitablemeans. Alternatively, a concentrate containing as much as about 20percent by weight of the additive in a polypropylene masterbatch may beprepared and be subsequently mixed with the resin. Furthermore, theclarifying additive (and other additives) may be present in any type ofstandard polyolefin additive form, including, without limitation,powder, prill, agglomerate, liquid suspension, and the like,particularly comprising dispersion aids such as polyolefin (e.g.,polyethylene) waxes, stearate esters of glycerin, montan waxes, mineraloil, and the like. Basically, any form may be exhibited by such acombination or composition including such combination made fromblending, agglomeration, compaction, and/or extrusion.

Other additives such as a transparent coloring agent or plasticizers(e.g., dioctyl phthalate, dibutyl phthalate, dioctyl sebacate, mineraloil, or dioctyl adipate), can be added to the composition of the presentinvention so long as they do not adversely affect the improvement oftransparency of the product. It has been found that plasticizers such asthose exemplified above may in fact aid in the improvement of thetransparency by the di-acetal. In particular, it is further contemplatedthat certain organoleptic improvement additives be added for the purposeof reducing the migration of degraded benzaldehydes from reaching thesurface of the desired article. The term “organoleptic improvementadditive” is intended to encompass such compounds and formulations asantioxidants (to prevent degradation of both the polyolefin and possiblythe target alditol derivatives present within such polyolefin), acidneutralizers (to prevent the ability of appreciable amounts of residualacids from attacking the alditol derivatives), and benzaldehydescavengers (such as hydrazides, hydrazines, and the like, to prevent themigration of foul tasting and smelling benzaldehydes to the targetpolyolefin surface). Such compounds and formulations can be added in anyamounts in order to provide such organoleptic improvements as needed.However, the amounts should not appreciably affect the haze results forthe target polyolefin itself. Thus, lower amounts on the order of fromabout 20 ppm to about 2,000 ppm of the total polyolefin component aredesired.

Polyolefin Formation and Testing

Transparent polypropylene optical disc storage units were producedcomprising DMDBS clarifying agents sample random copolymer polypropylene(RCP) resins, as noted below. The polypropylene was produced dry blendedin a Welex mixer at ˜2000 rpm, extruded through a single screw extruderat 400-450° F., and pelletized. Accordingly, batches of targetpolypropylene were produced in accordance with the following table:RANDOM COPOLYMER POLYPROPYLENE COMPOSITION TABLE Component AmountPolypropylene random copolymer flake (3% ethylene) 1000 g (MF = 12)Irganox ® 1010, Primary Antioxidant (from Ciba) 500 ppm Irgafos ® 168,Secondary Antioxidant (from Ciba) 1000 ppm Calcium Stearate, AcidScavenger 800 ppm DMDBS 2500 ppm

The base resin (random copolymer, hereinafter “RCP”) and all additiveswere weighed and then blended in a Welex mixer for 1 minute at about1600 rpm. All samples were then melt compounded on a Killion singlescrew extruder at a ramped temperature from about 204° to 232° C.through four heating zones. The melt temperature upon exit of theextruder die was about 246° C. The screw had a diameter of 2.54 cm and alength/diameter ratio of 24:1. Upon melting the molten polymer wasfiltered through a 60 mesh (250 micron) screen. The target storage unitsof this polypropylene material were then made through extrusion into anArburg 25 ton injection molder with the proper mold configuration. Themolder was set at a temperature anywhere between 190 and 260° C., with arange of 190 to 240° C. preferred, most preferably from about 200 to230° C. (for the Tables below, the standard temperature was 220; a #denotes a temperature 210, a A denotes a temperature of 200, and a @denotes a temperature of 230). The storage units had dimensions of about200 mm×200 mm×1.27 mm, and were made in a mold having a mirror finish.The mold cooling circulating water was controlled at a temperature ofabout 25° C.

The haze values were measured by ASTM Standard Test Method D1003-61“Standard Test Method for Haze and Luminous Transmittance of TransparentPlastics” using a BYK Gardner XL-211 Hazemeter. Nucleation capabilitieswere measured as polymer recrystallization temperatures (which indicatethe rate of polymer formation provided by the presence of the nucleatingadditive) by melting the target plaques, cooling the plaques at a rateof about 20° C./minute, and recording the temperature at which polymerre-formation occurs. The resultant haze of the product storage unitswere about 8.0%, a level of sufficient transparency to permitillumination of the optical discs stored therein for authenticitydetection in accordance with the inventive methods.

The optical discs themselves may be of any standard composition, whereinat least one plastic layer is coated with at least one informationlayer, which is further coated with at least one metallized layer, andwhich is further coated with a lacquer layer. Preferably, the plasticlayer is of a material having some compressibility, such as PERSPEX®(polymethyl methacrylate, or PUMA) and has a thickness between 5 mm and20 mm.

The metal layer is preferably nickel, although any other reflectivemetal may be utilized. The lacquer is preferably a methacrylate. Thegeneral production methods are as noted above within U.S. Pat. No.6,165,391, herein entirely incorporated by reference.

BRIEF DESCRIPTION OF THE DRAWINGS

The present invention will now be described in more detail by way ofexample only, with reference to the accompanying drawings wherein:

FIG. 1 is a cross-sectional view of a compact disc.

FIG. 2 is a top view of the inventive movable rosette arm storage unitconfiguration.

FIG. 3 is a partial aerial, partial side view of a preferred embodimentof a completely transparent polypropylene storage unit in its closedposition with an unimpeded spine and side walls for complete viewing ofinformational literature placed therein.

FIG. 4 shows a method of viewing a disc through a transparentpolypropylene storage unit to detect the identifying image on thesurface of the target disc.

DETAILED DESCRIPTION OF THE DRAWINGS

Referring now to FIG. 1, an optical disc is shown which comprises aplastic substrate 10 normally formed from polycarbonate and including aperipheral edge 8 and an upper surface 11 having a pattern of pitsformed therein which define a data recording. The pitted surface 11 isprovided with a metallic film 12 so as to provide a light reflectingsurface, the metallic layer 12 being covered by a protective layer oflacquer 13 which may be an ultraviolet light curable resin such as thatsold under the trade mark RENGOLUX®.

The resin is normally applied to the disc by spin coating, i.e. theresin is applied to the disc at a position slightly radially inwardlyfrom the radially innermost extremity of the metallized surface, thedisc being rotated at speed, such that the resin flows towards thecircumference of the disc, and is cured by exposure to ultravioletlight.

The manner in which the polycarbonate substrate 10 is formed is normallyby injection molding. A metal plate known as a stamper having a surfaceformed with an information layer is placed in the cavity of an injectionmould and polycarbonate material is injected into the mould.

The injection molding process produces a polycarbonate substrate bearingthe information layer and having a substantially flat surface and eventhickness, with maybe a variance of a few microns with the exception ofthe peripheral ridge 14 in the polycarbonate substrate which may be inthe region of 50 microns thicker than the average thickness of the discelsewhere.

FIG. 2 illustrates a desired structure of an inventive transparent cPPstorage unit 30. Such a unit 30 includes movable arms 32, 34 which areattached to the unit 30 via living hinges 33, 35. Although such livinghinges 33, 35 are preferred embodiments (since production of such amolded storage unit 30 is easier through a single mold), detachablehinges (not illustrated) may also be utilized. The discs 36, 38 areattached to the arms 32, 34 via individual rosettes 40 (other notillustrated). The moved arm 34 shows the ability to maneuver theparticular disc 38 outside the unit 30 in order to read and/or view thedesired promotional literature 52 which is held in place with brackets42, 44, 46, 48 to the unit 30. The other arm 32 may also be moved inlike fashion. The number of discs permitted in such a configuration maybe as many as six with individual moving arms attached at each segmentof the unit 30 separated by the spine hinge 50. Thus, the promotionalliterature 52 may be moved inside the unit 30 and easily read completelywither via movement of the individual arms 32, 34 or through theclarified wall of polypropylene on which the promotional literaturerests (not illustrated).

FIG. 3 depicts one preferred non-limiting design for the inventiveoptical disc storage unit. In particular, a cPP storage unit 80 isprovided including (here viewed in the closed position) a top flap 86attached via a living hinge 85 and a recessed portion 87 having a bottomside 88. The disc 82 is present within the storage unit 80.Informational literature 52 is present within said storage unit 80 andin contact with said top flap 86 as well as spine informationalliterature 53 is present within said storage unit 80 and in contact witha spine portion 102. Furthermore, said spine portion 102 includes nointernal or external reinforcements or injection points (not shown). Infact, the injection points (not shown) are present, in this embodiment,on the bottom side 88 of said recessed portion 87, thereby providing anunimpeded view of the informational literature 52 through each wall ofsaid storage unit 80 and said spine portion 102. Alternatively, a moresymmetrical storage unit may be utilized wherein any injection pointsmay be reduced in size and/or moved to a location sufficiently distantfrom the middle of the spine portion, again to provide the neededunimpeded view of any informational literature placed completely withinthe unit itself. Any combination thereof, including patterns in likemanner may be utilized as well for such a storage unit as long as thecompletely internally located informational literature is viewable andreadable while said unit is in its closed position.

FIG. 4 thus depicts another preferred embodiment utilizing the benefitsof a cPP storage unit 110. In closed position, a disc (partially shownas 116) resides within the unit 110, including promotional material 114present within the unit 110 as well. A cut-out portion 120 thus permitsviewing of an holographic image on the surface of the disc 116 foraesthetic, identification, or other desired purpose.

Thus, a new optical disc storage unit is provided, produced from atleast a majority of clarified polypropylene, permitting the completeinternal placement of any informational literature accompanying such adisc such that said literature is viewable and readable at any locationthrough the walls and spine portion of such a storage unit when closed.This, in turn, permits a reduction in cost for informational literatureprinting as a larger area of printable space is accorded as well as theability to remove the need for an outside jacket to hold title, cover,and other informational items. This inventive configuration alsoprovides a maximum utilization of space for the enjoyment and aestheticpleasure of the consumer as well with regards to the promotionalmaterial, or other like supplied articles accompanying thecommercialized disc.

There are, of course, many alternative embodiments and modifications ofthe present invention which are intended to be included within thespirit and scope of the following claims.

1-4. (canceled)
 5. A transparent polypropylene-containing digital videostorage system free from any transparent sleeves attached thereto, saidstorage system comprising a container adapted to house at least oneoptical disc, the container having a first side comprising a wall and asecond side comprising a wall, said sides being separated by at leastone living hinge and a transparent spine portion substantially free ofrefractive impediments, the system further comprising a single sheet ofinformational literature disposed between the disc and the containersuch that said single sheet of informational literature is in directcontact with said walls and said spine portion such that when saidcontainer is in its closed position said informational literature can beviewed and read through said walls and said spine portion and whereinthe storage system further includes at least one peripheral edge,including at least one means for holding an optical disc, said at leastone optical disc holding means being either permanently or temporarilyattached to said at least one peripheral edge via a hinge, wherein saidoptical disc may be maneuvered outside of said container whilesimultaneously being held within said holding means which in turnremains attached to said at least one peripheral edge and wherein saidat least one optical disc holding means comprises a tapered arm having abase attached to said at least one peripheral edge and a progressivelytapered body portion extending away from the base to a distal end. 6.The storage system of claim 5, wherein said at least one optical disc issupported at the distal end.
 7. A transparent polypropylene-containingdigital video storage system free from any transparent sleeves attachedthereto, said storage system comprising a container adapted to house atleast one optical disc, the container having a first side comprising awall and a second side comprising a wall, said sides being separated byat least one living hinge and a transparent spine portion substantiallyfree of refractive impediments, the system further comprising a singlesheet of informational literature disposed between the disc and thecontainer such that said single sheet of informational literature is indirect contact with said walls and said spine portion such that whensaid container is in its closed position said informational literaturecan be viewed and read through said walls and said spine portion andwherein the storage system further includes at least one peripheraledge, including a plurality of hinging arms for supporting opticaldiscs, wherein at least a portion of the arms are attached to said atleast one peripheral edge via hinges, wherein said optical discs may bemaneuvered outside of said container while simultaneously being heldwithin said holding means which in turn remains attached to said atleast one peripheral edge.
 8. The storage system of claim 7, wherein atleast a portion of the hinging arms are of tapered construction having abase attached to at least one peripheral edge and a progressivelytapered body portion extending away from the base to a distal end forsupporting an optical disc.
 9. A transparent polypropylene-containingdigital video storage system free from any transparent sleeves attachedthereto, said storage system comprising a container adapted to house atleast one optical disc, the container having a first side comprising awall and a second side comprising a wall, said sides being separated byat least one living hinge and a non-reinforced transparent spine portionsubstantially free of refractive impediments, the system furthercomprising a single sheet of informational literature disposed betweenthe disc and the container such that said single sheet of informationalliterature is in direct contact with said walls and said spine portionsuch that when said container is in its closed position saidinformational literature can be viewed and read through said walls andsaid spine portion and wherein the container further includes at leastone peripheral edge, including at least one means for holding an opticaldisc, said at least one optical disc holding means being attached tosaid at least one peripheral edge via a hinge, wherein said optical discmay be maneuvered outside of said container while simultaneously beingheld within said holding means which in turn remains attached to said atleast one peripheral edge and wherein said at least one optical discholding means comprises a tapered arm having a base attached to said atleast one peripheral edge and a progressively tapered body portionextending away from the base to a distal end.
 10. The storage system ofclaim 9, wherein said at least one optical disc is supported at thedistal end.
 11. A transparent polypropylene-containing digital videostorage system free from any transparent sleeves attached thereto, saidstorage system comprising a container adapted to house at least oneoptical disc, the container having a first side comprising a wall and asecond side comprising a wall, said sides being separated by at leastone living hinge and a non-reinforced transparent spine portionsubstantially free of refractive impediments, the system furthercomprising a single sheet of informational literature disposed betweenthe disc and the container such that said single sheet of informationalliterature is in direct contact with said walls and said spine portionsuch that when said container is in its closed position saidinformational literature can be viewed and read through said walls andsaid spine portion and wherein the container further includes at leastone peripheral edge, including a plurality of hinging arms forsupporting optical discs, wherein at least a portion of the arms areattached to at least one peripheral edge via hinges, wherein saidoptical discs may be maneuvered outside of said container whilesimultaneously being held within said holding means which in turn remainattached to said at least one peripheral edge.
 12. The storage system ofclaim 11, wherein at least a portion of the hinging arms are of taperedconstruction having a base attached to at least one peripheral edge anda progressively tapered body portion extending away from the base to adistal end for supporting an optical disc.
 13. A digital video storagesystem free from any transparent sleeves attached thereto, said storagesystem comprising a container for housing at least one optical disc anda single sheet of informational literature wherein at least a portion ofthe informational literature is disposed between the optical disc and aninterior surface of the container, the container having a first sidecomprising a wall and a second side comprising a wall, said sides beingseparated by at least one living hinge, the container further having atransparent spine portion substantially free of refractive impediments,wherein the single sheet of informational literature is disposeddiscontinuously between the optical disc and the interior surface of thecontainer such that when said container is in its closed position, saidinformational literature is in direct contact with said walls and saidspine portion of said storage unit and said informational literature canbe viewed and read through said walls and said spine portion of saidstorage unit and such that portions of the optical disc not covered bythe informational literature are viewable through said walls and saidspine portion of said storage unit such that holographic images on saidportions of the optical disc not covered by the informational literatureare viewable through said walls and said spine portion.